Fatigue crack growth fcg is one of the essential properties to be. Sensitivity analysis of fatigue crack growth model for api steels in gaseous hydrogen. The result of hydrogen embrittlement is that components crack and fracture at stresses less than the yield strength of the metal. In order to investigate the influence of hydrogen on the fatigue strength of type 304 metastable austenitic stainless steel, specimens were cathodically charged with hydrogen. Hydrogen induced cracking hic in the oil and gas industry. Standardized fatigue crack growth tests were performed in gaseous hydrogen at. Fatigue crack growth fcg tests for compacttension specimens of lowcarbon steel were performed under various combinations of hydrogen pressures 0. Hydrogen experts testing, consulting, and analysis by top phds. Development of a model for hydrogen assisted fatigue crack growth in api pipeline steel article pdf available in journal of pressure vessel technology 1402 december 2017 with 205 reads. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement.
Type 304 stainless steel and ductile cast iron dci. Defects hydrogen cracks in steels identification twi. Yip sandia national laboratories livermore, ca doe hydrogen pipeline working group meeting aiken, sc september 2526, 2007. Particularly common to the oil and gas industry where the use of steel. To justify the interpretation of the mechanism based on the hydrogenenhanced successive fatigue crack growth hesfcg model, using both internal and external hydrogen, some critical experiments were performed on two types of material. The world leader in gases for industry, health and the environment 22. Fatigue testing of a 2507 super duplex stainless steel m92 in flowing hydrogen gas i. Hydrogen embrittlement of steel industrial metallurgists. In parallel with the aforementioned proposals based on the hesfcg model, somerday et al. Hydrogen cracking of welds in duplex stainless steels, proc conf. The effects of purity and pressure on hydrogen embrittlement of metallic. Hydrogen induced cracking steel features, applications and. Aug 17, 2012 this paper presents a new mechanism controlling the acceleration of fatigue crack growth of a hydrogencharged highstrength steel bearing steel sae52100.
Hydrogen cracking of ferriticaustenitic stainless steel. Chemistry physics science and technology, general cracking materials dynamic testing methods dynamic testing engineering fatigue materials fatigue testing machines gas pipelines hydrogen as fuel hydrogen. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. The fatigue crack growth testing was performed on sa516 grade 70 steel, which was procured from a commercial. Gaseous hydrogenassisted fatigue crack growth in x52. Hydrogen blistering occurs because of the diffusion of atomic hydrogen inside metal. And yet, its poorly understood by most engineers and rarely accounted for. Optimizing measurement of fatigue crack growth relationships. Measure fatigue crack growth rates of x100 steel in h 2. Fatigue and fracture performance of high strength pipeline. Mechanical properties of structural steels in hydrogen. One such integrity assessment methodology for steel hydrogen pipelines was recently published in the asme b31. The crack growth rates in hydrogen gas exceed those in helium gas at all. Hydrogen gas enhances the fatigue crack growth rate dadn 17, 19.
Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hydrogeninduced ductility loss of austenitic stainless. Gaseous hydrogen embrittlement of materials in energy. G2mt labs provides unparalleled expertise in hydrogen testing, consulting, and analysis from hightemperature hydrogen attack to embrittlement, hydrogen plays a critical role in the life, and often the failure, of many metals. The crack growth rates in hydrogen gas exceed those in argon gas at. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Test specimens were oriented in the steel pipe such that cracks propagated either parallel or perpendicular to the banded pearlite. Subcritical crack growth tests conducted in air on specimens with internal hydrogen showed modest effects of the trapped residual hydrogen, however, tests of precharged material in. K relationship for hy100 steel is demonstrated in figure 3. K relationships were measured for an x52 friction stir welded pipe tested in 21 mpa hydrogen gas at a frequency of 1 hz and r. Somerday, assessing gaseous hydogen assisted fatigue crack growth susceptibility of pipeline steel weld fusion zones and heat affected zones. The individual hydrogen atoms within the metal gradually recombine to form hydrogen molecules, creating pressure from within the metal. Sandia national laboratories features three systems for materials testing in h. Sensitivity analysis of fatigue crack growth model for api.
Fatigue crack initiation and growth in a crmo steel under hydrogen. The nanohardness distribution around the fatigue crack tip is dependent on the plastic zone and different microstructures in materials. Predictive modeling of hydrogen assisted fatigue crack growth in pipeline steel thesis directed by dr. May 19, 2009 in essence, hic testing is actually an evaluation of the steel for susceptibility to hydrogen embrittlement. Fracture of materials and structures from micro to macro scale, dresden, germany, august 30september 3. The fatigue crack growth rate dadn versus stressintensity factor range dk relationship is a necessary input to structural integrity models applied to steel hydrogen pipelines.
J steel in 100 mpa hydrogen gas following article kd10. Friction stir welded steel pipelines were tested in high pressure hydrogen gas to examine the effects of hydrogen accelerated fatigue crack growth. The crack susceptibility of a wide range of weld metals deposited by various processes was examined. Somerday, brian, san marchi, chris, and nibur, kevin. Hydrogen embrittlement of structural steels doe hydrogen and. Challenges associated with a hydrogen economy are substantial, ranging from hydrogen generation and storage to transportation. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. The effect of hydrogen gas on the crack growth rate vs stressintensity factor range. Higherstrength 34crmo4 steel generally more susceptible to hydrogen accelerated fatigue crack growth than lowerstrength sa372 gr. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Hydrogen experts testing, consulting, and analysis by. K mpa m 12 5 10 20 50 crack growth rate, dadn mmcycle 107 106 10.
The effects of purity and pressure on hydrogen embrittlement of metallic materials id 149. Herein, the hydrogen embrittlement of a heataffected zone haz was examined using slow strain rate tension in situ hydrogen charging. Todd murray the growing government and industry interest in vehicles powered by hydrogen fuel cells has warranted research in recent years on use of the existing oil and natural gas pipeline infrastructure for widespread hydrogen fuel transport. Hydrogen cracking may also be called cold cracking or delayed cracking. Proceedings of the asme 20 pressure vessels and piping conference. Predictive modeling of hydrogen assisted fatigue crack growth. In this issue, the characteristic features and principal causes of hydrogen cracks are described. The effect of highpressure hydrogen gas on the crack growth rate vs stressintensity factor range. Banded ferritepearlite x65 pipeline steel was tested in high pressure hydrogen gas to evaluate the effects of oriented pearlite on hydrogen assisted fatigue crack growth. The test specimens were extracted from the steel test rings and designed according to. A num ber of reports on this subject are avail able, but the results tend to be incon sistent. Technical reference on hydrogen compatibility of materials. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. Corrosionpedia what is hydrogeninduced cracking hic.
Fatigue crack initiation and growth in a crmo steel under. A new method of nanohardness distribution for investigating the hydrogen effect on the fatigue crack in austenitic stainless steels was developed. Hydrogen embrittlement of type 304l stainless steel. Mechanical properties of structural steels in hydrogen b. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Nov 19, 2015 somerday, brian, bortot, paolo, and felbaum, john. Shinozaki k, ke l and north t h, hydrogen cracking in duplex stainless steel weld metal, welding journal 1992, 71. Capability for fatigue crack growth testing in h 2 successfully developed. Three dimensionally complicated shape of a primary crack and secondary cracks were observed in hydrogen charged specimens. Fatigue crack growth fcg tests for compact tension ct specimens of an annealed, lowcarbon steel, jissm490b were performed under various combinations of hydrogen pressures ranging from 0. Pdf hydrogen enhanced fatigue crack growth rates in a. Report by journal of research of the national institute of standards and technology. Hydrogen cracking of ferriticaustenitic stainless steel weld. A study of hydrogen crackin in underwater steel welds.
Bechtle s, kumar m, somerday bp, launey me, ritchie ro 2009. Fatigue crack growth acceleration due to hydrogen in type. Measured fatigue crack growth laws for x52 steel base metal and erw seam weld fatigue crack growth laws for x52 base metal and erw similar in h 2 notable variability in data from replicate tests for both base metal and erw in h 2 stress intensity factor range. Hydrogen gas enhances the fatigue crack growth rate dadn. Hydrogenassisted crack growth in the heataffected zone. J steel in 100 mpa hydrogen gas following article kd10, 20 asme pressure vessels and piping division conference, asme, new york, pvp2097455, 20. Optimizing measurement of fatigue crack growth relationships for crmo pressure vessel steels in hydrogen gas. Optimizing measurement of fatigue crack growth relationships for crmo pressure vessel steels in hydrogen gas brian somerday, paolo bortot and john felbaum. Measurement of fatigue crack growth relationships in hydrogen. Hydrogen embrittlement is a metals loss of ductility and reduction of load bearing capability due to the absorption of hydrogen atoms or molecules by the metal.
Hydrogen induced cracking steel features, applications. Effects of hydrogen pressure, test frequency and test. Atomic hydrogen is formed by the hydrogen ions accepting electrons from a cathodic surface or environment. Development of a model for hydrogenassisted fatigue crack. Hydrogen enhanced fatigue crack growth rates in a ferritic fe3 wt. Crubbs and seth1 contend that the hydrogen cracking problem in carbon steel welds is minor unless the carbon. Journal of solid mechanics and materials engineering 1. E x t r u s io d i r e c t i o n lo r i e n t a t i o n. Gaseous hydrogen at pressure of 45 mpa 6500 psi r 0.
This paper presents a new mechanism controlling the acceleration of fatigue crack growth of a hydrogencharged highstrength steel bearing steel sae52100. Hydrogen embrittlement accounted for in design and safety qualification of components through materials testing. Demonstrated ability to measure fatigue crack growth of pressure vessel steels in highpressure h. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Fatigue crack growth testing can be conducted more efficiently, i. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. Nov 26, 2018 both hydrogen and martensite greatly influence the nanohardness and the gradient of hydrogen concentration near the crack tip, which will have a significant effect on the fatigue crack growth. To establish novel criteria for authorizing various austenitic stainless steels for use in highpressure gaseous hydrogen, a. Proceedings of the asme 2015 pressure vessels and piping conference. Fatigue crack growth testing was previously performed on a gas metal arc welded x65 pipe and the results can be found in the fy 2014 annual report.
The susceptibilities of these classes of steel to hydrogen embrittlement as measured by the effects of hydrogen on fracture initiation and subsequent crack growth are discussed when the steels are tested in hydrogen gas, when the hydrogen has been introduced by charging and when the hydrogen embrittlement is associated with stress corrosion. Hydrogen embrittlement of grain boundaries in nickel. Hydrogen effects on x80 steel mechanical properties. However, since fatigue crack growth rates of steels in hydrogen gas are known to decrease as load cycle frequency increases, the test frequency must be limited so that measured crack growth rates are not unrealistically low. In this study, insitu fatigue crack growth rate testing on compact. To elucidate the mechanism of the degradation by hydrogen, the. The test procedure involves the evaluation of resistance of pressure vessel steel plate and pipework steels to hydrogen reduced cracking caused by hydrogen absorption from aqueous sulfide corrosion. Steels for seamless hydrogen pressure vessels corrosion. Hydrogen embrittlement of type 304l stainless steel corrosion. Atomic hydrogen so formed is the only chemical form of hydrogen capable of entering steels microstructure by diffusion penetration, as hydrogen gas in. Chemistry physics science and technology, general fatigue materials analysis fatigue testing machines pipeline construction pipelines design and construction. Nanoindentation could provide a possibility to quantitatively estimate the size of the plastic zone and. Furthermore, since the vessel steel is exposed to high purity hydrogen gas, crack initiation and.
Crack growth paths and slip bands morphology were changed by the hydrogencharging. Hydrogenenhanced fatigue crack growth in steels and its. The interaction of corrosion fatigue and stresscorrosion. Address potential fatigue crack growth aided by hydrogen embrittlement, particularly in welds enable a pipeline reliabilityintegrity framework that accommodates hydrogen embrittlement ensure relevance to h. Materials testing and variables governing fracture. Jan 17, 2014 somerday, brian, san marchi, chris, and nibur, kevin. Chemistry physics science and technology, general cracking materials dynamic testing methods dynamic testing engineering fatigue materials fatigue testing machines gas pipelines hydrogen. To provide engineering data useful in the design, manufacture, and operation of seamless pressure vessels, extensive tests have been conducted in hydrogen at pressures ranging from 3000 to 14,000 psi 21 to 97 mnm 2 with precracked specimens of steels having a wide range of mechanical properties. Measurement of fatigue crack growth rates for sa372 gr. Development of a model for hydrogenassisted fatigue crack growth in api pipeline steel article pdf available in journal of pressure vessel technology 1402 december 2017 with 205 reads. Hydrogen delivery somerday sandia national laboratories. A new mechanism in hydrogenenhanced fatigue crack growth. The critical stressintensity level at which crack propagation spontaneously.
For slow strain rate tensile ssrt test in hydrogen gas, the degradation in relative reduction in area rra of 300series austenitic stainless steels is mainly attributed to hydrogen assisted surface crack growth hascg accompanied by quasicleavages. What is metric for qualifying steels for h2 pipelines. Hydrogenassisted crack growth in the heataffected zone of. Address potential fatigue crack growth aided by hydrogen embrittlement, particularly in welds. The hydrogen embrittlement susceptibility of the base metal and the haz samples increased with increasing current density. Shinozaki k, ke l and north t h, hydrogen cracking in duplex stainless steel weld metal, welding journal 1992, 71, 11, 387s396s. Identify pathways for reducing the cost of steel hydrogen.